The organocatalytic addition of bis(arylsulfonyl)methane to α,β-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols

被引：39

作者：

Garcia Ruano, Jose Luis ^{[1
]}

Marcos, Vanesa ^{[1
]}

Aleman, Jose ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ C 1, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 29期

关键词：

MICHAEL ADDITION; ASYMMETRIC-SYNTHESIS; PHEROMONE SYNTHESIS; CONJUGATE ADDITION; SEX-PHEROMONE; BEETLE;

D O I：

10.1039/b908963b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An indirect organocatalytic method for the beta-methylation of alpha,beta-unsaturated aldehydes that involves the addition of bis(arylsulfonyl)methane catalyzed by prolinol derivatives and further elimination of the chameleonic sulfonyl groups is presented.

引用

页码：4435 / 4437

页数：3

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