Thermal desorption spectroscopy of alkanethiol self-assembled monolayer on Au(111)

被引:102
作者
Nishida, N [1 ]
Hara, M [1 ]
Sasabe, H [1 ]
Knoll, W [1 ]
机构
[1] SAITAMA UNIV,GRAD SCH SCI & ENGN,URAWA,SAITAMA 338,JAPAN
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1996年 / 35卷 / 11期
关键词
alkanethiol self-assembled monolayer; thermal desorption spectroscopy; dimerization; self-exchange; dialkyl disulfide; adsorption kinetics;
D O I
10.1143/JJAP.35.5866
中图分类号
O59 [应用物理学];
学科分类号
摘要
The adsorption and desorption of octadecanethiol (CH3(CH2)(17)SH: monomer) self-assembled monolayers (SAMs) on Au(lll) have been investigated by thermal desorption spectroscopy (TDS). Two desorption peaks of dioctadecyl disulfide ((CH3(CH2)(17)S)(2)(+): dimer(+)) exhibiting different sticking behaviors have been identified in the TDS spectra, while the desorption of octadecanethiol (CH3(CH)(17)SH+: monomer(+)) occurred at a lower temperature than that of the dimer(+). The desorption activation energy and the pre-exponential factor for each peak were estimated assuming first- and second-order reactions. The analysis results suggest that both alkyl thiolate (RS-Au) with strong chemisorption and dialkyl disulfide (RS-SR: dimer) with relatively weak adsorption co-exist in the alkanethiol SAM on An. The total amount of relatively weakly adsorbed dimers increased appreciably in a slow reaction step, while the monolayer thickness remained almost constant after SAM formation. This result suggests that dimer molecules are formed in the monolayer. This formation of weakly adsorbed dimers is strongly related to the self-exchange phenomena in SAM films reported by Schlenoff et al. [J. Am. Chem. Sec. 117 (1995) 12528].
引用
收藏
页码:5866 / 5872
页数:7
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