Redox-active aza-crown ethers derived from biphenyl. Electrochemical and solution studies of complexation

被引：10

作者：

Costero, AM

Monrabal, E

Sanjuan, F

机构：

[1] Fac Farm, Dept Quim Organ, Burjassot 46100, Spain

[2] Univ Politecn Valencia, Dept Quim, E-46071 Valencia, Spain

来源：

TETRAHEDRON | 1999年 / 55卷 / 52期

关键词：

D O I：

10.1016/S0040-4020(99)00988-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new ligands 4 and 5, containing in their structures aza-crown ethers moieties in addition to tetramethylbenzidine units, have been prepared. Their ability to complex transition metal cations has been studied by NMR and electrochemical techniques. Ligand 5 gives rise to two diastereoisomeric complexes with Cd(NO3)(2). (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：15141 / 15150

页数：10

相关论文

共 15 条

[1] STABILITY IN AQUEOUS-SOLUTION OF SOME COMPLEXES OF HEAVY-METALS WITH DIAZA-POLYOXAMACROCYCLIC LIGANDS [J].

ARNAUDNEU, F ;

SPIESS, B ;

SCHWINGWEILL, MJ .

HELVETICA CHIMICA ACTA, 1977, 60 (08) :2633-2643

[2] SOLVENT EFFECTS IN THE COMPLEXATION OF [2]-CRYPTANDS AND RELATED MONOCYCLES WITH TRANSITION-METAL AND HEAVY-METAL CATIONS [J].

ARNAUDNEU, F ;

SPIESS, B ;

SCHWINGWEILL, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5641-5645

[3] Electrochemical molecular recognition: pathways between complexation and signalling [J].

Beer, PD ;

Gale, PA ;

Chen, GZ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (12) :1897-1909

[4]

Boulas PL, 1998, ANGEW CHEM INT EDIT, V37, P216, DOI 10.1002/(SICI)1521-3773(19980216)37:3<216::AID-ANIE216>3.0.CO

[5]

2-P

[6] Redox-active crown ethers derived from biphenyl, electrochemical and spectroscopic study of binding processes with alkali, alkali-earth and mercury salts [J].

Costero, AM ;

Andreu, C ;

Martínez-Máñez, R ;

Soto, J ;

Ochando, LE ;

Amigó, JM .

TETRAHEDRON, 1998, 54 (28) :8159-8170

[7]

COSTERO AM, UNPUB J CHEM SOC DA

[8] SUPERQUAD - AN IMPROVED GENERAL PROGRAM FOR COMPUTATION OF FORMATION-CONSTANTS FROM POTENTIOMETRIC DATA [J].

GANS, P ;

SABATINI, A ;

VACCA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06) :1195-1200

[9] SYNTHESES AND BINDING-PROPERTIES OF BIBRACHIAL LARIAT ETHERS (BIBLES) - SURVEY OF SYNTHETIC METHODS AND CATION SELECTIVITIES [J].

GATTO, VJ ;

ARNOLD, KA ;

VISCARIELLO, AM ;

MILLER, SR ;

MORGAN, CR ;

GOKEL, GW .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (26) :5373-5384

[10] FORMATION OF COMPLEXES BETWEEN AZA DERIVATIVES OF CROWN ETHERS AND PRIMARY ALKYLAMMONIUM SALTS .4. DIAZA-18-CROWN-6 DERIVATIVES [J].

HODGKINSON, LC ;

JOHNSON, MR ;

LEIGH, SJ ;

SPENCER, N ;

SUTHERLAND, IO ;

NEWTON, RF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (09) :2193-2202