Complementary multicomplexation of desymmetrized 2,2′-bipyridine ligands on square planar Pd(II) Centers

被引：14

作者：

Tominaga, M

Kusukawa, T

Sakamoto, S

Yamaguchi, K

Fujita, M

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Corp, JST, CREST, Bunkyo Ku, Tokyo 1138656, Japan

[3] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 2638522, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 07期

关键词：

D O I：

10.1246/cl.2004.794

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon complexation with Pd(II) ion, desymmetrized chelating ligand, 6-methyl-2,2'-bipyridine (1), gives only anti Pd.(1)(2)(2+) complex. This regioselective complexation is applied to complementary multicomplexation of liner molecular strands: namely, a strand containing two methyl-substituted 2,2'-bipyridine units is selectively complexed on Pd(II) with its counterpart strand in which methyl groups are complementarily substituted.

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页码：794 / 795

页数：2

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