6-azabicyclo[3.1.0]hex-3-en-2-ol derivatives, photochemically generated building blocks for bicyclic beta-lactams

被引：20

作者：

Glarner, F

Thornton, SR

Scharer, D

Bernardinelli, G

Burger, U

机构：

[1] UNIV GENEVA,DEPT ORGAN CHEM,CH-1211 GENEVA 4,SWITZERLAND

[2] UNIV GENEVA,LAB XRAY CRYSTALLOG,CH-1211 GENEVA 4,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1997年 / 80卷 / 01期

关键词：

D O I：

10.1002/hlca.19970800112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compounds 4 are obtained by photolysis of simple N-alkylpyridinium salts in H2O or alcohol. On reaction with [Fe-2(CO)(9)] in THF, 4 gives bicyclic tricarbonyliron complexes 13a-d, which on oxidative decomplexation with eerie ammonium nitrate afford cis-fused cyclopenteno-beta-lactams 15a-d.

引用

页码：121 / 127

页数：7

共 31 条

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