An enantiocontrolled synthesis of pyrrolizidines, (-)-platynecine and (-)-hadinecine

被引：20

作者：

Kang, SH

Kim, GT

Yoo, YS

机构：

[1] Department of Chemistry, Korea Adv. Inst. Sci. and Technol.

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(96)02371-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trisubstituted allylic alcohols 13 and 14 have been converted into a single isomeric trans-oxazoline 16 via an intramolecular iodoamidation of the corresponding trichloroacetimidates, which have been elaborated into (-)-platynecine 1 and (-)-hadinecine 2 via a common intermediate pyrrolizidine 3. (C) 1997, Elsevier Science Ltd. All rights reserved.

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页码：603 / 606

页数：4

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