Kinetic study on the pyrolysis of cellulose using the novel continuous cross-flow moving bed type differential reactor

被引:14
作者
Yamaguchi, Yohsuke
Fushimi, Chihiro
Tasaka, Kazuhiko
Furusawa, Takeshi
Tsutsumi, Atsushi
机构
[1] Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
[2] Japan Sci & Technol Agcy, JST, CREST, Bunkyo Ku, Kawaguchi 3320012, Japan
关键词
D O I
10.1021/ef050334f
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The pyrolysis of cellulose was studied using a novel CCDR in which tar and gases can be fractionated according to the reaction time. Similar trends of evolution behavior were observed for both tar and low-molecular-weight gases in the pyrolysis of cellulose at 673 K. The evolution of tar and low-molecular-weight gases achieve a peak at 20-30 s, converting depolymerizing cellulose to nascent char. The dehydration of nascent char produced by depolymerization and devolatilization was found to take place after the devolatilization is completed.
引用
收藏
页码:2681 / 2685
页数:5
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