Access to the superstrong segregation regime with nonionic ABC copolymers

被引：92

作者：

Lodge, TP

Hillmyer, MA

Zhou, ZL

Talmon, Y

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

[3] Technion Israel Inst Technol, Dept Chem Engn, IL-32000 Haifa, Israel

来源：

MACROMOLECULES | 2004年 / 37卷 / 18期

关键词：

D O I：

10.1021/ma048708b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The access to the superstrong segregation regime (SSSR) with nonionic, flexible coil block copolymers, by use of three-monomers ABC triblock copolymers was discussed. An access to the SSSR consisted of a water soluble poly(ethylene oxide) (O) block, hydrocarbon, polystyrene (S) and a fluorppolymer (F). A linear OSB triblock prepared by controlled anionic polymerization, with block molecular weights of 13200 (N o=300),4700 (N s=45) and 1300 (N b=24. It was observed that a new domain of block copolymers phase behavior, the superstrong segregation regime was accessed in a controled fashion with nonionic triblock copolumers.

引用

页码：6680 / 6682

页数：3

共 9 条

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