Steam reforming of ethanol on Ni/MgO catalysts:: H2 production for MCFC

被引：115

作者：

Freni, S

Cavallaro, S

Mondello, N

Spadaro, L

Frusteri, F

机构：

[1] Inst CNR TAE, I-98126 Messina, Italy

[2] Univ Messina, Dipartimento Chim Ind & Ingn Mat, I-98166 Messina, Italy

来源：

JOURNAL OF POWER SOURCES | 2002年 / 108卷 / 1-2期

关键词：

Ni/MgO; H-2; production; ethanol; steam reforming; fuel cell;

D O I：

10.1016/S0378-7753(02)00004-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

H-2 production by ethanol steam reforming in simulating molten carbonate fuel cell (MCFC) conditions was explored. Ni/MgO catalysts exhibit very high selectivity to H-2 and CO, as a consequence of their low tendency to promote carbon monoxide methanation and ethanol decomposition reactions. Coke formation is strongly depressed due to the benefits induced by the use of basic carrier which positively modify the electronic properties of supported Ni. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：53 / 57

页数：5

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