Critical evaluation of stability constants of metal-imidazole and metal-histamine systems

被引：103

作者：

Sjoberg, S

机构：

来源：

PURE AND APPLIED CHEMISTRY | 1997年 / 69卷 / 07期

关键词：

D O I：

10.1351/pac199769071549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermodynamic data for the proton and metal ion complexation equilibria of imidazole ( 1.3 - diazole, glyoxaline) and histamine ( 4-imidoazolethylamine, 4 - ( 2' - aminoethyl ) imidazole) have been collected and critically evaluated. The literature search has been performed by using IUPAC's ''Stability Constants Database'' and covers the literature until 1992. Important criteria for acceptance comprise specification of the essential reaction conditions, the correctness of calibration techniques and appropriate equilibrium analysis of experimental data. Recommended values with respect to proton - ligand and metal ion - ligand equilibria have been tabulated. Furthermore, the medium dependence of these reactions has been evaluated using an extended Debye - Huckel expression.

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页码：1549 / 1570

页数：22

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