Microstructural characterization of bulk Ti3AlC2 ceramics

被引:39
作者
Ma, XL [1 ]
Zhu, YL [1 ]
Wang, XH [1 ]
Zhou, YC [1 ]
机构
[1] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1080/14786430410001716197
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The microstructural characteristics of the bulk Ti3AlC2 ceramic, synthesized by a solid-liquid reaction and simultaneous in-situ hot pressing, have been studied by electron diffraction and high-resolution transmission electron microscopy. It was found that the as-synthesized ceramic is fully dense and free from amorphous phase at the grain boundaries. The ceramic is predominantly a single phase of hexagonal Ti3AlC2 with a minor volume of tetragonal Al3Ti and cubic TiC. The Al3Ti grains are crystallographically independent of the Ti3AlC2, whereas TiC is intergrown with Ti3AlC2, forming thin platelets and maintaining a close orientational relationship with the Ti3AlC2 matrix.
引用
收藏
页码:2969 / 2977
页数:9
相关论文
共 21 条
[1]   SYNTHESIS OF TITANIUM-SILICON CARBIDE [J].
ARUNAJATESAN, S ;
CARIM, AH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (03) :667-672
[2]   Processing and characterization of Ti2AlC, Ti2AlN, and Ti2AlC0.5N0.5 [J].
Barsoum, MW ;
Ali, M ;
El-Raghy, T .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2000, 31 (07) :1857-1865
[3]   Fabrication and characterization of M2SnC (M = Ti, Zr, Hf and Nb) [J].
Barsoum, MW ;
Yaroschuk, G ;
Tyagi, S .
SCRIPTA MATERIALIA, 1997, 37 (10) :1583-1591
[4]   Oxidation of Ti3SiC2 in air [J].
Barsoum, MW ;
ElRaghy, T ;
Ogbuji, LUJT .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (07) :2508-2516
[5]   Synthesis and characterization of a remarkable ceramic: Ti3SiC2 [J].
Barsoum, MW ;
ElRaghy, T .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (07) :1953-1956
[6]  
Chen KX, 2002, RARE METAL MAT ENG, V31, P20
[7]   Ultra-low friction for a layered carbide-derived ceramic, Ti3SiC2, investigated by lateral force microscopy (LFM) [J].
Crossley, A ;
Kisi, EH ;
Summers, JWB ;
Myhra, S .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1999, 32 (06) :632-638
[8]  
JEICHKO W, 1967, MONATSCHATTE CHEM, V98, P329
[9]   Ti3SiC2:: A damage tolerant ceramic studied with nano-indentations and transmission electron microscopy [J].
Kooi, BJ ;
Poppen, RJ ;
Carvalho, NJM ;
De Hosson, JTM ;
Barsoum, MW .
ACTA MATERIALIA, 2003, 51 (10) :2859-2872
[10]   Microstructure of Ti3SiC2-based ceramics [J].
Morgiel, J ;
Lis, J ;
Pampuch, R .
MATERIALS LETTERS, 1996, 27 (03) :85-89