Direct synthesis and crystal, structure of the polymeric thiocyanate complexes of copper(I)

被引：29

作者：

Babich, OA ^{[1
]}

Kokozay, VN ^{[1
]}

Pavlenko, VA ^{[1
]}

机构：

[1] KIEV SHEVCHENKO UNIV,DEPT CHEM,KIEV 252033,UKRAINE

来源：

POLYHEDRON | 1996年 / 15卷 / 16期

关键词：

D O I：

10.1016/0277-5387(95)00556-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds Cu(SCN). CH3CN (1) and [(CH3)(3)NH](+) [Cu-2(SCN)(3)](-) (2) have been synthesized using a direct method of interaction and characterized by X-ray crystallography. The planar Cu2S2 units with the copper-copper distances 3.095 (1) and 2.972 Angstrom (2) form the basis of both structures. Complex 1 consists of the infinite puckered layers with the interlayer distance 6.657 Angstrom. The three-dimensional polymeric anion [Cu-2(SCN)(3)]- in compound 2 comprises two crystallographically independent copper(I) atoms and two bridging thiocyanate groups with different coordinations. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2727 / 2731

页数：5

共 5 条

[1]

FRENZ BA, 1978, COMPUTING CRYSTALLOG, P64

[2] BONDING PROPERTIES OF THIOCYANATE GROUPS IN COPPER(II) AND COPPER(I) COMPLEXES [J].