Tetraalkylammonium N-chloro-p-toluenesulfonamide as aminating agent of olefins

被引：13

作者：

Cenini, S ^{[1
]}

Penoni, A ^{[1
]}

Tollari, S ^{[1
]}

机构：

[1] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 124卷 / 2-3期

关键词：

tetraalkylammonium N-chloro-p-toluenesulfonamide; metalloporphyrins; amination; olefins;

D O I：

10.1016/S1381-1169(97)00091-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The alkylammonium salt of chloramine-T has been used as aminating agent of olefins in the presence of M(TPP)Cl (M = Fe, Mn; TPP = tetraphenylporphyrin) as catalyst. Main products were the corresponding allylamine, the aziridine, the alpha-chloro-amine derived by attack of chloride ion on the less substituted carbon of the aziridine, and toluene-p-sulfonamide. The reaction gave reasonable yields of the products with unsubstituted cyclic olefins, while poor results have been obtained with norbornene and 1-hexene. (C) 1997 Elsevier Science B.V.

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页码：109 / 113

页数：5

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