Study of the chemical copolymerization of 2-aminoterephthalic acid and aniline.: Synthesis and copolymer properties

被引：38

作者：

Arias-Pardilla, J.

Salavagione, H. J.

Barbero, C.

Morallon, E.

Vazquez, J. L.

机构：

[1] Univ Nacl Rio Cuarto, Dept Quim, RA-5800 Rio Cuarto, Argentina

[2] Univ Alicante, Dept Quim Fis, E-03080 Alicante, Spain

[3] Univ Alicante, Inst Univ Mat, E-03080 Alicante, Spain

来源：

EUROPEAN POLYMER JOURNAL | 2006年 / 42卷 / 07期

关键词：

conducting polymers; polyaniline; copolymerization; electroactivity; solubility; fluorescence;

D O I：

10.1016/j.eurpolymj.2006.02.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aniline (ANI) and 2-aminoterephthalic acid (2ATA) copolymers, with different compositions, were prepared by chemical oxidative polymerization varying the feed ratio. The new materials have been characterized by techniques such as XPS, FTIR, Raman spectroscopies and thermal analysis. It has been checked that 2ATA units are included in the polymer backbone. Different properties have been studied as solubility, conductivity, optical absorption, fluorescence and electroactivity. The copolymers are soluble in aqueous alkaline medium and show clear electroactivity in aqueous acid medium. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1521 / 1532

页数：12

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