Synthesis and reactions of highly strained 2,3-bridged 2H-azirines

被引：28

作者：

Banert, Klaus ^{[1
]}

Meier, Barbara ^{[1
]}

机构：

[1] Tech Univ Chemnitz, Lehrstuhl Organ Chem, D-09111 Chemnitz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 24期

关键词：

azides; cycloaddition; dimerization; nitrogen heterocycles; strained molecules;

D O I：

10.1002/anie.200600483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Take the strain: Despite extreme ring strain and reactivity, the heterocycles 2, which are easily obtained from azides 1 and detectable by NMR spectroscopy, can be converted stereoselectively by novel addition and cycloaddition reactions. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

页码：4015 / 4019

页数：5

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