Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex

被引：82

作者：

Davies, Noel W.

Frey, Alistair S. P.

Gardiner, Michael G.

Wang, Jun

机构：

[1] Univ Tasmania, Cent Sci Lab, Hobart, Tas 7001, Australia

[2] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 46期

关键词：

D O I：

10.1039/b611784h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A macrocyclic organosamarium(II) complex has been shown to provide the first example of the reductive disproportionation of carbon dioxide, giving a bimetallic carbonate complex and carbon monoxide in a facile reaction under ambient conditions.

引用

页码：4853 / 4855

页数：3

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