Applicability of the fractal FHH equation

被引:66
作者
Sahouli, B [1 ]
Blacher, S [1 ]
Brouers, F [1 ]
机构
[1] UNIV ORAN,LOCM,ORAN,ALGERIA
关键词
D O I
10.1021/la962119k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The current work deals with the applicability of the fractal version of the Frenkel-Halsey-Hill (FHH) theory of multilayer adsorption. The concept of the standard isotherm is introduced to examine the weakness of this equation when the solid-gas potential controls the adsorption process of gas on a given solid. The results of the determination of the fractal dimension of typical samples of carbon blacks, activated carbon, and aerogels (mixed SiO2-ZrO2 and pure silica) are given. They show that the fractal dimension depends critically of the coverage exponent s for a flat surface of the same chemical nature.
引用
收藏
页码:4391 / 4394
页数:4
相关论文
共 44 条
[1]   MOLECULAR FRACTAL SURFACES [J].
AVNIR, D ;
FARIN, D ;
PFEIFER, P .
NATURE, 1984, 308 (5956) :261-263
[2]   AN ISOTHERM EQUATION FOR ADSORPTION ON FRACTAL SURFACES OF HETEROGENEOUS POROUS MATERIALS [J].
AVNIR, D ;
JARONIEC, M .
LANGMUIR, 1989, 5 (06) :1431-1433
[3]  
AVNIR D, 1983, NOUV J CHIM, V7, P71
[4]   ANALYSIS OF NITROGEN ADSORPTION ISOTHERMS ON POROUS AND NONPOROUS SILICAS BY BET AND ALPHAS METHODS [J].
BHAMBHANI, MR ;
TURK, DH ;
SING, KSW ;
CUTTING, PA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1972, 38 (01) :109-+
[5]   On the texture characterization of mixed SiO2-ZrO2 aerogels using the nitrogen adsorption-desorption isotherms: Classical and fractal methods [J].
Blacher, S ;
Pirard, R ;
Pirard, JP ;
Sahouli, B ;
Brouers, F .
LANGMUIR, 1997, 13 (05) :1145-1149
[6]   MULTILAYER ADSORPTION OF NITROGEN AND ALKANES BY NON-POROUS CARBONS AND SILICAS [J].
CARROTT, PJM ;
SING, KSW .
PURE AND APPLIED CHEMISTRY, 1989, 61 (11) :1835-1840
[7]   HENRY LAW OF ADSORPTION ON A FRACTAL SURFACE [J].
COLE, MW ;
HOLTER, NS ;
PFEIFER, P .
PHYSICAL REVIEW B, 1986, 33 (12) :8806-8809
[8]   FRACTAL ANALYSIS OF COMMERCIAL AND PYROLYTIC CARBON-BLACKS USING NITROGEN ADSORPTION DATA [J].
DARMSTADT, H ;
ROY, C ;
KALIAGUINE, S ;
SAHOULI, B ;
BLACHER, S ;
PIRARD, R ;
BROUERS, F .
RUBBER CHEMISTRY AND TECHNOLOGY, 1995, 68 (02) :330-341
[9]  
DEGENNES PG, 1985, PHYSICS DISORDERED M
[10]  
Frenkel Y.I., 1946, KINETIC THEORY LIQUI