Synthesis and catalytic activity of sodium-magnesium orthophosphates of different stoichiometry

被引：4

作者：

Aramendia, MA

Borau, V

Jimenez, C

Marinas, JM

Romero, FJ

机构：

[1] Department of Organic Chemistry, Faculty of Sciences, University of Córdoba, E-14004 Cordoba, Avda San Alberto Magno s/n

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 58卷 / 01期

关键词：

orthophosphates; cyclohexanol; cyclohexanone;

D O I：

10.1007/BF02071123

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reports on the synthesis and characterization of various mixed orthophosphates [NaMgPO4, Na4Mg(PO4)(2) and NaMg4(PO4)(3)] obtained from freshly prepared Mg-3(PO4)(2) gel by using various treatments. The solids exhibit excellent selectivity in the gas-phase conversion of cyclohexanol (CHOL) to cyclohexanone (CHONE).

引用

页码：183 / 191

页数：9

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