A new type of multilayer system-silver(I) complexes of polycyclic aromatic compounds

被引：223

作者：

Munakata, M ^{[1
]}

Wu, LP

Ning, GL

机构：

[1] Kinki Univ, Dept Chem, Higashiosaka, Osaka 5778502, Japan

[2] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 198卷

关键词：

silver(I) compounds; polycyclic aromatics; multilayer compounds; cation-pi interaction; triple-layer compounds; double-layer compounds;

D O I：

10.1016/S0010-8545(99)00162-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new type of silver(I) coordination complex derived from silver(I) perchlorate (or triflate) and polycyclic aromatic compounds is reviewed. Structural studies by single-crystal X-ray diffraction have shown that all compounds contain extended one- to three-dimensional structures in which several metal atoms are sandwiched between two fused polycyclic systems. Special attention is paid to the combination of the plasticity of the metal ion, coordinative versatility of the aromatic ligand, solvent effect and the nature of the counteranions for designing metal complexes with a wide range of infinite frameworks. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：171 / 203

页数：33

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