Characterization of calcareous deposits in artificial sea water by impedances techniques:: 2-deposit of Mg(OH)2 without CaCO3

被引:129
作者
Deslouis, C
Festy, D
Gil, O
Maillot, V
Touzain, S
Tribollet, B
机构
[1] UPR 15 CNRS, F-75252 Paris 05, France
[2] IFREMER, Ctr Brest, Lab Mat Marins, F-29280 Plouzane, France
[3] Univ La Rochelle, Lab Mat Milieux Agressifs, La Rochelle, France
关键词
magnesium hydroxide deposit; impedances; sea-water; mass transport; porous layer;
D O I
10.1016/S0013-4686(99)00403-X
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mg2+ and the corresponding Mg(OH), play roles in the transformation of calcareous deposits in sea water. In this paper, only Mg(OH)(2) deposition is considered. The composition of other components involved (except Ca2+ ions) also follows ASTM standards. A model of Mg(OH)(2) film formation is presented by considering this film as a porous layer. The basic technique to investigate the Mg(OH)(2) film formation has been chronoamperometry used in conjunction with ac impedance and EHD impedance techniques to complement the information about the morphology of the magnesium hydroxide deposit. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1837 / 1845
页数:9
相关论文
共 16 条
  • [1] INSITU SURFACE PH MEASUREMENT DURING ELECTROLYSIS USING A ROTATING PH ELECTRODE
    DELIGIANNI, H
    ROMANKIW, LT
    [J]. IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1993, 37 (02) : 85 - 95
  • [2] THE CATHODIC MASS-TRANSPORT PROCESS DURING ZINC CORROSION IN NEUTRAL AERATED SODIUM-SULFATE SOLUTIONS
    DESLOUIS, C
    DUPRAT, M
    TULETTOURNILLON, C
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 181 (1-2): : 119 - 136
  • [3] Kinetics and characterisation of calcareous deposits under cathodic protection in natural sea water
    Deslouis, C
    Doncescu, A
    Festy, D
    Gil, O
    Maillot, V
    Touzain, S
    Tribollet, B
    [J]. ELECTROCHEMICAL METHODS IN CORROSION RESEARCH VI, PTS 1 AND 2, 1998, 289-2 : 1163 - 1180
  • [4] Impedance techniques at partially blocked electrodes by scale deposition
    Deslouis, C
    Gabrielli, C
    Keddam, M
    Khalil, A
    Rosset, R
    Tribollet, B
    Zidoune, M
    [J]. ELECTROCHIMICA ACTA, 1997, 42 (08) : 1219 - 1233
  • [5] Interfacial pH measurement during the reduction of dissolved oxygen in a submerged impinging jet cell
    Deslouis, C
    Frateur, I
    Maurin, G
    Tribollet, B
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (04) : 482 - 492
  • [6] TRANSIENT MASS-TRANSFER AT A COATED ROTATING-DISK ELECTRODE - DIFFUSION AND ELECTROHYDRODYNAMIC IMPEDANCES
    DESLOUIS, C
    TRIBOLLET, B
    DUPRAT, M
    MORAN, F
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (10) : 2496 - 2501
  • [7] DESLOUIS C, 1991, ADV ELECTROCHEMICAL, V2, P205
  • [8] DESLOUIS C, 1891, ELECTROCHIM ACTA, V43, P1998
  • [9] Study of calcium carbonate scales by electrochemical impedance spectroscopy
    Gabrielli, C
    Keddam, M
    Khalil, A
    Rosset, R
    Zidoune, M
    [J]. ELECTROCHIMICA ACTA, 1997, 42 (08) : 1207 - 1218
  • [10] LEVART E, 1976, J ELECTROANAL CHEM, V70, P117, DOI 10.1016/0368-1874(76)85058-7