Highly reactive intermediate-functionalized gold clusters: synthesis and immobilization on silica supports through amide-forming coupling

被引:19
作者
Akamatsu, K
Hasegawa, J
Nawafune, H
Katayama, H
Ozawa, F
机构
[1] Konan Univ, High Technol Res Ctr, Fac Sci & Engn, Kobe, Hyogo 6588501, Japan
[2] Osaka City Univ, Grad Sch Engn, Dept Appl Chem, Sumiyoshi Ku, Osaka 5588585, Japan
关键词
D O I
10.1039/b207167c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gold clusters functionalized with interchain carboxylic anhydride over their entire surface have been successfully immobilized on amine-functionalized silica supports through amide-forming coupling, providing ordered two-dimensional arrangements of cluster monolayers, which might find utility in the development of artificial nanostructures for nanoelectronic device applications.
引用
收藏
页码:2862 / 2865
页数:4
相关论文
共 51 条
[1]   Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters [J].
Andres, RP ;
Bielefeld, JD ;
Henderson, JI ;
Janes, DB ;
Kolagunta, VR ;
Kubiak, CP ;
Mahoney, WJ ;
Osifchin, RG .
SCIENCE, 1996, 273 (5282) :1690-1693
[2]   Nanocomposites by electrostatic interactions: 1. Impact of sublayer quality on the organization of functionalized nanoparticles on charged self-assembled layers [J].
Auer, F ;
Scotti, M ;
Ulman, A ;
Jordan, R ;
Sellergren, B ;
Garno, J ;
Liu, GY .
LANGMUIR, 2000, 16 (20) :7554-7557
[3]   Self-assembly of nanoparticles into structured spherical and network aggregates [J].
Boal, AK ;
Ilhan, F ;
DeRouchey, JE ;
Thurn-Albrecht, T ;
Russell, TP ;
Rotello, VM .
NATURE, 2000, 404 (6779) :746-748
[4]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[5]   Self-assembled gold nanoparticle thin films with nonmetallic optical and electronic properties [J].
Brust, M ;
Bethell, D ;
Kiely, CJ ;
Schiffrin, DJ .
LANGMUIR, 1998, 14 (19) :5425-5429
[6]   Chemoselective immobilization of gold nanoparticles onto self assembled monolayers [J].
Chan, EWL ;
Yu, LP .
LANGMUIR, 2002, 18 (02) :311-313
[7]   Self-assembling of monolayer-protected gold nanoparticles [J].
Chen, SW .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (04) :663-667
[8]   Ion-induced rectification of nanoparticle quantized capacitance charging in aqueous solutions [J].
Chen, SW ;
Pei, RJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (43) :10607-10615
[9]  
COOKE RG, 1995, CHEM IND, P142
[10]   INFRARED SPECTRA OF SOME CYCLIC ANHYDRIDES [J].
DAUBEN, WG ;
EPSTEIN, WW .
JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (10) :1595-1596