Pressure dependence of H solubility in magnesiowustite up to 25 GPa: Implications for the storage of water in the Earth's lower mantle

[1] The solubility of hydrogen in (Mg0.93Fe0.07)O was studied from 5 to 25 GPa at 1200degreesC under oxidizing conditions, using FTIR spectroscopy on quenched single crystals. OH solubility increases with increasing pressure, concomitant with a decrease in ferric iron content. This result suggests that under lower mantle conditions, the charge neutrality condition could change from [Fe-Me] = 2[ V"(Me)] to [(OH)(O)] = 2[V"(Me)], which would have important implications for the rheology of that region. The OH solubility data are well explained by incorporation of H as isolated hydroxyl groups via reduction of ferric iron. The amount of H incorporated at 25 GPa and 1200degreesC is similar to 100 H/10(6) Me (Me = Mg, Fe), i. e. similar to 20 ppm wt H2O, under water- saturated conditions. When integrated over the entire mass of the lower mantle, these 20 ppm wt H2O amount to about 7.3 x 10(18) kg H2O, a storage capacity of similar to0.5% of the ocean mass.