A versatile new monomer family:: Functionalized 4-vinyl-1,2,3-triazoles via click chemistry

被引：158

作者：

Thibault, Raymond J.

Takizawa, Kenichi

Lowenheilm, Peter

Helms, Brett

Mynar, Justin L.

Frechet, Jean M. J.

Hawker, Craig J. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 37期

关键词：

D O I：

10.1021/ja0648209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using facile, highly modular synthetic approaches, a new monomer family based on a 1,2,3-triazole-4-vinyl building block has been prepared, and various functional derivatives have been obtained. Subsequent homo- and copolymerization of these novel functionalized monomers gives polymeric materials with unique physical properties, combining many attractive features of more traditional monomers, such as styrene, vinylpyridine, and meth/acrylates. Copyright © 2006 American Chemical Society.

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页码：12084 / 12085

页数：2

相关论文

共 18 条

[1] Organic azides:: An exploding diversity of a unique class of compounds [J].

Bräse, S ;

Gil, C ;

Knepper, K ;

Zimmermann, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (33) :5188-5240

[2]

CHITTABOINA S, 2005, TETRAHEDRON LETT, V127, P14942

[3] A graph-structural method for prediction of polymer properties [J].

Corrêa, RO ;

Telles, AS ;

Ourique, JE .

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2004, 21 (04) :621-628

[4] Click chemistry in materials synthesis.: 1.: Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition [J].

Díaz, DD ;

Punna, S ;

Holzer, P ;

Mcpherson, AK ;

Sharpless, KB ;

Fokin, VV ;

Finn, MG .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (17) :4392-4403

[5] The convergence of synthetic organic and polymer chemistries [J].

Hawker, CJ ;

Wooley, KL .

SCIENCE, 2005, 309 (5738) :1200-1205

[6] Dendronized linear polymers via "click chemistry" [J].

Helms, B ;

Mynar, JL ;

Hawker, CJ ;

Fréchet, JMJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (46) :15020-15021

[7] Highly active water-soluble olefin metathesis catalyst [J].

Hong, SH ;

Grubbs, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) :3508-3509

[8] Orthogonal approaches to the simultaneous and cascade functionalization of macromolecules using click chemistry [J].

Malkoch, M ;

Thibault, RJ ;

Drockenmuller, E ;

Messerschmidt, M ;

Voit, B ;

Russell, TP ;

Hawker, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (42) :14942-14949

[9] One-pot tandem living radical polymerisation-Huisgens cycloaddition process (''click'') catalysed by N-alkyl-2-pyridylmethanimine/Cu(I)Br complexes [J].

Mantovani, G ;

Ladmiral, V ;

Tao, L ;

Haddleton, DM .

CHEMICAL COMMUNICATIONS, 2005, (16) :2089-2091

[10] Modular synthesis of block copolymers via cycloaddition of terminal azide and alkyne functionalized polymers [J].

Opsteen, JA ;

van Hest, JCM .

CHEMICAL COMMUNICATIONS, 2005, (01) :57-59