Living anionic homopolymerization and block copolymerization of 4-vinylpyridine at ''elevated'' temperature and its characterization by size exclusion chromatography

被引：43

作者：

Creutz, S ^{[1
]}

Teyssie, P ^{[1
]}

Jerome, R ^{[1
]}

机构：

[1] UNIV LIEGE,CERM,B-4000 LIEGE,BELGIUM

来源：

MACROMOLECULES | 1997年 / 30卷 / 01期

关键词：

D O I：

10.1021/ma9610931

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The anionic polymerization of 4-vinylpyridine (4VP) has been investigated in 9/1 pyridine/THF at 0 degrees C. After characterization of the living character of 4VP polymerization, its copolymerization with tert-butyl methacrylate (tBMA) has been carried out also successfully. Their relative reactivity ratios have been determined. Solvent composition as well as temperature have been varied in order to evaluate their influence on the final molecular characteristics of the polymers. Finally, a new SEC methodology in 8/1/1 N,N-dimethylformamide/triethylamine/pyridine has been developed.

引用

页码：1 / 5

页数：5

共 19 条

[1] CREUTZ S, UNPUB MACROMOLECULES
[2] NEW INITIATOR SYSTEM FOR THE LIVING ANIONIC-POLYMERIZATION OF TERT-ALKYL ACRYLATES
FAYT, R
FORTE, R
JACOBS, C
JEROME, R
OUHADI, T
TEYSSIE, P
VARSHNEY, SK
[J]. MACROMOLECULES, 1987, 20 (06) : 1442 - 1444
[3] REACTION-KINETICS OF POLYMER SUBSTITUENTS - MACROMOLECULAR STERIC HINDRANCE EFFECT IN QUATERNIZATION OF POLY(VINYLPYRIDINES)
FRERE, Y
GRAMAIN, P
[J]. MACROMOLECULES, 1992, 25 (12) : 3184 - 3189
[4] HUYNHBA G, 1987, RECENT ADV ANIONIC P, P173
[5] Jerome R., 1987, NATO ASI SER C-MATH, VC215, P101
[6] KLEIN JW, 1991, POLYMER, V32, P2279
[7] KINETICS OF ANIONIC POLYMERIZATION AND COPOLYMERIZATION OF VINYL PYRIDINES - PENULTIMATE EFFECTS
LEE, CL
SMID, J
SZWARC, M
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (485): : 1192 - &
[8] STAR-BRANCHED POLYMERS .2. LINKING REACTION INVOLVING 2-VINYL AND 4-VINYL PYRIDINE AND DIENYLLITHIUM AND STYRYLLITHIUM CHAIN ENDS
LUXTON, AR
QUIG, A
DELVAUX, MJ
FETTERS, LJ
[J]. POLYMER, 1978, 19 (11) : 1320 - 1324
[9] INFLUENCE OF SOLVENT POLARITY ON ELUTION VOLUME IN THE CASE OF POLAR POLYMERS
MENCER, HJ
GRUBISICGALLOT, Z
[J]. JOURNAL OF LIQUID CHROMATOGRAPHY, 1979, 2 (05): : 649 - 662
[10] ANIONIC SYNTHESIS AND CHARACTERIZATION OF POLY(4-VINYLPYRIDINE)-POLY(DIMETHYLSILOXANE) BLOCK COPOLYMERS
NUGAY, N
KUCUKYAVUZ, Z
KUCUKYAVUZ, S
[J]. POLYMER INTERNATIONAL, 1993, 32 (01) : 93 - 96

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