Shape and magnetic properties of single-crystalline hematite (α-Fe2O3) nanocrystals

被引:104
作者
Cao, Huaqiang [1 ]
Wang, Guozhi [1 ]
Zhang, Lei [1 ]
Liang, Yu [1 ]
Zhang, Sichun [1 ]
Zhang, Xinrong [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
magnetic properties; nanocrystals; Raman spectroscopy; transmission electron microscopy; X-ray diffraction;
D O I
10.1002/cphc.200600130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Unusual magnetic behavior of α-Fe2O3: Rice- (a) and cube-shaped (b) single-crystalline α-Fe2O3 nanostructures (see microstructure images) are obtained by a new hydrothermal reaction route. Different magnetic anisotropies are observed for the rice- and cube-shaped α-Fe2O3 nanocrystals. This behavior offers possibilities for technological applications of α-Fe 2O3 with magnetic properties tailored by shape-controlled synthesis. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1897 / 1901
页数:5
相关论文
共 47 条
[1]   SINGLE-CRYSTAL RAMAN SPECTRA OF NEARLY OPAQUE MATERIALS - IRON(III) OXIDE AND CHROMIUM(III) OXIDE [J].
BEATTIE, IR ;
GILSON, TR .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (06) :980-&
[2]  
Bersani D, 1999, J RAMAN SPECTROSC, V30, P355, DOI 10.1002/(SICI)1097-4555(199905)30:5<355::AID-JRS398>3.0.CO
[3]  
2-C
[4]   Growth and optical properties of wurtzite-type CdS nanocrystals [J].
Cao, Huaqiang ;
Wang, Guozhi ;
Zhang, Sichun ;
Zhang, Xinrong ;
Rabinovich, Daniel .
INORGANIC CHEMISTRY, 2006, 45 (13) :5103-5108
[5]   Single-crystal dendritic micro-pines of magnetic α-Fe2O3:: Large-scale synthesis, formation mechanism, and properties [J].
Cao, MH ;
Liu, TF ;
Gao, S ;
Sun, GB ;
Wu, XL ;
Hu, CW ;
Wang, ZL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) :4197-4201
[6]   Preparation and magnetic properties of Fe3O4 nanostructures grown by electrodeposition [J].
Carlier, D ;
Terrier, C ;
Arm, C ;
Ansermet, JP .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (03) :C43-C46
[7]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[8]  
Chikazumi S., 1997, PHYS FERROMAGNETISM
[9]  
deFaria DLA, 1997, J RAMAN SPECTROSC, V28, P873, DOI 10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO
[10]  
2-B