Speciation of aluminium in tea infusions studied by size exclusion chromatography with detection by post-column reaction

被引:36
作者
Flaten, AK [1 ]
Lund, W [1 ]
机构
[1] UNIV OSLO, DEPT CHEM, N-0315 OSLO, NORWAY
关键词
size exclusion chromatography; tea infusions; aluminium species; post-column reaction; pyrocatechol violet;
D O I
10.1016/S0048-9697(97)00239-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Aluminium-organic species in tea infusions were studied by size exclusion chromatography, using a Superose 12 HR column, a mobile phase of 0.12 mol l(-1) tris(hydroxymethyl)aminomethane adjusted to pH 5.5 and detection by UV-visible spectrophotometry. Aluminium was detected after post-column reaction with pyrocatechol violet at 585 nm and the organic material was detected at 280 nn. Teas of different origin were analyzed; the results indicate that aluminium is bound to the same relatively narrow size-range of large organic molecules in the tea infusions, irrespective of the origin of the tea. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:21 / 28
页数:8
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