Bis[2-methoxy-6-(3-pyridylmethyliminomethyl)phenolato-κ2N,O]copper(II)

被引：3

作者：

Chen, Xiaodan ^{[1
]}

Sun, Yu ^{[2
]}

Yao, Qingzhao ^{[1
]}

Zhang, Huaihong ^{[1
]}

Liang, Qing ^{[1
]}

机构：

[1] Southeast Univ, Coll Chem & Chem Engn, Ordered Matter Sci Res Ctr, Nanjing 210096, Peoples R China

[2] Jiangsu Univ, Coll Pharm, Zhenjiang 212013, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

基金：

中国国家自然科学基金;

关键词：

CRYSTAL;

D O I：

10.1107/S1600536809052349

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cu(C14H13N2O2)(2)], the Cu-II ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN2O2] coordination geometry, with the Cu-II ion coordinated by two 2-methoxy-6-(3-pyridylmethyliminomethyl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)degrees between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component

引用

页码：M39 / U481

页数：10

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