Supramolecular networks based on octacyanometallates of Mo and W

被引：25

作者：

Sieklucka, B ^{[1
]}

Podgajny, R ^{[1
]}

Korzeniak, T ^{[1
]}

Przychodzen, P ^{[1
]}

Kania, R ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

COMPTES RENDUS CHIMIE | 2002年 / 5卷 / 10期

关键词：

supramolecular coordination compounds coordination polymers; crystal engineering; octacyanometallates;

D O I：

10.1016/S1631-0748(02)01428-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of cyano-bridged discrete coordination architectures and polymeric coordination networks based on [M(CN)(8)](3-/4-) (M = Mo and W) molecular building blocks has been systematically investigated in order to obtain some basic information useful for crystal engineering of supramolecular coordination networks. The research is illustrated by concentrating on the superstructural diversity that has been exhibited in 0D architectures generated by cis and trans octahedral precursors, 1D and 2D architectures generated by Cu(II) centres, as well as in 2D structure generated by octahedral node of [Mn(H2O)(6)](2+) and geometrically anisotropic [W(CN)(6)(bpy)](2-) (bpy = 2,2'-bipyridine).

引用

页码：639 / 649

页数：11

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