[Fe(CNXyl)4]2-:: An isolable and structurally characterized homoleptic isocyanidemetalate dianion

被引：31

作者：

Brennessel, William W. ^{[1
]}

Ellis, John E. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 04期

关键词：

anions; iron; isocyanide ligands; reduction; subvalent compounds;

D O I：

10.1002/anie.200603746

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) World's record: The first isolation and structural characterization of a homoleptic isocyanidemetalate dianion has been achieved with [Fe(CNXyl)4]2- (Xyl = 2,6-dimethylphenyl; see structure, Fe red, N blue, C gray). Spectral and structural data indicate that metal-to-isocyanide back-bonding in this electron-rich species is the largest ever observed in a homoleptic isocyanide complex containing only terminally bound ligands. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：598 / 600

页数：3

共 25 条

[1] First homoleptic isocyanides of niobium and tantalum
Barybin, MV
Young, VG
Ellis, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (39) : 9237 - 9238
[2] First paramagnetic zerovalent transition metal isocyanides. Syntheses, structural characterizations, and magnetic properties of novel low-valent isocyanide complexes of vanadium
Barybin, MV
Young, VG
Ellis, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (19) : 4678 - 4691
[3] Beck W., 1991, ANGEW CHEM, V103, P173
[4] BRENNESSEL WW, UNPUB
[5] FORMATION OF HIGHLY FUNCTIONALIZED METAL-BOUND ACETYLENES BY REDUCTIVE COUPLING OF CARBON-MONOXIDE AND METHYL ISOCYANIDE LIGANDS
CARNAHAN, EM
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) : 4166 - 4174
[6] CRYSTAL-STRUCTURE OF NA-2FE(CO)4.1.5(C-4H-8O-2) - DISTORTION OF [FE(CO)4]2- ANION IN SOLID-STATE
CHIN, HB
BAU, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) : 2434 - 2439
[7] (ISOCYANIDE)RUTHENATE ANALOGS OF TETRACARBONYLFERRATE
CORELLA, JA
THOMPSON, RL
COOPER, NJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (01): : 83 - 84
[8] Cotton, 1959, PROGRESS INORGANIC C, V1, P283
[9] C-13 NMR-STUDY OF ISONITRILE TRANSITION-METAL COMPLEXES
CRONIN, DL
WILKINSON, JR
TODD, LJ
[J]. JOURNAL OF MAGNETIC RESONANCE, 1975, 17 (03) : 353 - 361
[10] CHEMISTRY OF METAL-CARBONYL ANIONS .2. SYNTHESIS AND REACTIONS OF PENTACARBONYLMETALLATE DIANIONS OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN WITH METALLIC MONOHALIDES
ELLIS, JE
HENTGES, SG
KALINA, DG
HAGEN, GP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 97 (01) : 79 - 93

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