Preparation of 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] and magnetic properties of its 1:1 copper(II) complex after photolysis

被引：11

作者：

Karasawa, S

Tanaka, M

Koga, N

Iwamura, H

机构：

[1] KYUSHU UNIV,FAC PHARMACEUT SCI,HIGASHI KU,FUKUOKA 81282,JAPAN

[2] KYUSHU UNIV,INST FUNDAMENTAL RES ORGAN CHEM,HIGASHI KU,FUKUOKA 81282,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a702168b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of a paramagnetic 1:1 complex of copper(II) with 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] produces a ferromagnetic chain consisting of an alternating array of 3d spins of Cu-II and 2p spins of the quintet dicarbenes.

引用

页码：1359 / 1360

页数：2

共 10 条

[1] A NEW TYPE OF MIXED-LIGAND COMPLEX WITH NITROXYL RADICALS [J].

BURDUKOV, AB ;

OVCHARENKO, VI ;

IKORSKI, VN ;

PERVUKHINA, NV ;

PODBEREZSKAYA, NV ;

GRIGOREV, IA ;

LARIONOV, SV ;

VOLODARSKY, LB .

INORGANIC CHEMISTRY, 1991, 30 (05) :972-976

[2] MAGNETIC PHASE-TRANSITION AND LOW-TEMPERATURE EPR-SPECTRA OF A ONE-DIMENSIONAL FERRIMAGNET FORMED BY MANGANESE(II) AND A NITRONYL NITROXIDE [J].

CANESCHI, A ;

GATTESCHI, D ;

RENARD, JP ;

REY, P ;

SESSOLI, R .

INORGANIC CHEMISTRY, 1989, 28 (10) :1976-1980

[3] THE CHEMISTRY AND MAGNETIC-PROPERTIES OF METAL NITRONYL NITROXIDE COMPLEXES [J].

CANESCHI, A ;

GATTESCHI, D ;

REY, P .

PROGRESS IN INORGANIC CHEMISTRY, 1991, 39 :331-429

[4] ELECTRON-PARAMAGNETIC-RES STUDIES OF LONG-RANGE INTRAMOLECULAR ELECTRON ELECTRON EXCHANGE INTERACTION [J].

EATON, GR ;

EATON, SS .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (03) :107-113

[5] FERROMAGNETIC AND FERRIMAGNETIC ORDERING IN A 2-DIMENSIONAL NETWORK FORMED BY MANGANESE(II) AND 1,3,5-TRIS[P(N-TERT-BUTYL-N-OXYAMINO)PHENYL]BENZENE [J].

INOUE, K ;

IWAMURA, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :3173-3174

[6] MOLECULAR DESIGN AND MODEL EXPERIMENTS OF FERROMAGNETIC INTERMOLECULAR INTERACTION IN THE ASSEMBLY OF HIGH-SPIN ORGANIC-MOLECULES - GENERATION AND CHARACTERIZATION OF THE SPIN STATES OF ISOMERIC BIS(PHENYLMETHYLENYL)[2.2]PARACYCLOPHANES [J].

IZUOKA, A ;

MURATA, S ;

SUGAWARA, T ;

IWAMURA, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (09) :2631-2639

[7]

KARASAWA S, UNPUB

[8] EXCHANGE INTERACTION IN METAL RADICAL SYSTEMS - CHLORO(MESO-TETRAPHENYLPORPHYRINATO)CHROMIUM(III)S AND (HEXAFLUOROACETYLACETONATO)MANGANESE(II) LIGATED WITH 3-(N-OXY-N-TERT- AND 4-(N-OXY-N-TERT-BUTYLAMINO)PYRIDINES [J].

KITANO, M ;

ISHIMARU, Y ;

INOUE, K ;

KOGA, N ;

IWAMURA, H .

INORGANIC CHEMISTRY, 1994, 33 (26) :6012-6019

[9]

KOGA N, 1996, ANGEW CHEM INT EDIT, V36, P755

[10]

SANO Y, IN PRESS J AM CHEM S

← 1 →