Hydrodynamic voltammetry with channel microband electrodes: The simulation of voltammetric waveshapes

被引：33

作者：

Bidwell, MJ ^{[1
]}

Alden, JA ^{[1
]}

Compton, RG ^{[1
]}

机构：

[1] UNIV OXFORD,PHYS & THEORET CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 417卷 / 1-2期

关键词：

channel microband electrodes; hydrodynamic voltammetry; simulation; strongly implicit procedure; multigrid method MGD1; current-voltage waveshapes;

D O I：

10.1016/S0022-0728(96)04739-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The strongly implicit procedure and the multigrid method MGD1 are used to simulate the steady-state current-voltage response of channel electrodes, including under conditions where diffusional effects in the direction of flow are significant. Reversible, quasi-reversible and irreversible heterogeneous kinetics are all considered.

引用

页码：119 / 128

页数：10

共 32 条

[1] Hydrodynamic voltammetry with channel microband electrodes: Axial diffusion effects
Alden, JA
Compton, RG
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 404 (01) : 27 - 35
[2] The multigrid method, MGD1: An efficient and stable approach to electrochemical modelling. The simulation of double electrode problems
Alden, JA
Compton, RG
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 415 (1-2): : 1 - 12
[3] NUMERICAL-SIMULATION OF CONVECTIVE DIFFUSION AT A RECTANGULAR CHANNEL FLOW ELECTRODE
ANDERSON, JL
MOLDOVEANU, S
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 179 (1-2) : 107 - 117
[4] [Anonymous], RES CHEM KINET
[5] THEORY OF ULTRAMICROELECTRODES
AOKI, K
[J]. ELECTROANALYSIS, 1993, 5 (08) : 627 - 639
[6] Bidwell MJ, 1996, J ELECTROANAL CHEM, V414, P247
[7] Studies in heterogeneous equilibria. Part II - The kinetic interpretation of the nernst theory of electromotive force.
Butler, JAV
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1924, 19 (03): : 0729 - 0733
[8] Studies in heterogeneous equilibria. Part III. A kinetic theory of reversible oxidation potentials at inert electrodes.
Butler, JAV
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1924, 19 (03): : 0734 - 0739
[9] Voltammetry under high mass transport conditions. The application of the high speed channel electrode to the reduction of pentafluoronitrobenzene
Coles, BA
Dryfe, RAW
Rees, NV
Compton, RG
Davies, SG
McCarthy, TD
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 411 (1-2): : 121 - 127
[10] HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - POTENTIAL STEP TRANSIENTS
COMPTON, RG
DRYFE, RAW
ALDEN, JA
REES, NV
DOBSON, PJ
LEIGH, PA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (04) : 1270 - 1275

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