Self-assembled monolayers on engineering metals: Structure, derivatization, and utility

被引：149

作者：

Van Alsten, JG ^{[1
]}

机构：

[1] Dupont Co, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

LANGMUIR | 1999年 / 15卷 / 22期

关键词：

D O I：

10.1021/la981694g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A methodology for the formation and derivatization of self-assembled monolayers (SAMs) of alkyl phosphonic acids on common engineering metals such as steel, stainless steel, aluminum, copper, and brass is described. This methodology is shown to be a versatile route for surface modification of such substrates. alpha,omega-Metal bisphosphonate SAMs are shown to be receptive to complexation by organic acids and acid-containing polymers such as fluoropolymers and ethylene-co-methacrylic acid. This latter attribute is exploited in the construction of polymer/SAM/metal interfaces of surprising durability. The durability of the interface is a strong function of the SAM chain length.

引用

页码：7605 / 7614

页数：10

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