Electrical conductivity of molten LnCl(3) and M(3)LnCl(6) compounds (Ln=La,Ce,Pr,Nd; M=K,Rb,Cs)

被引：22

作者：

Gaune, P ^{[1
]}

GauneEscard, M ^{[1
]}

Rycerz, L ^{[1
]}

Bogacz, A ^{[1
]}

机构：

[1] WROCLAW TECH UNIV,INST INORGAN CHEM & MET RARE ELEMENTS,PL-50370 WROCLAW,POLAND

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1996年 / 235卷 / 02期

关键词：

electrical conductivity; LnCl(3); molten complex chlorides of rare earth and alkali metals; CHLORIDES; SYSTEMS;

D O I：

10.1016/0925-8388(95)02090-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrical conductivities of molten lanthanide chlorides LnCl(3) and definite compounds M(3)LnCl(6) (where Ln = La, Ce, Pr, Nd and M = K, Rb, Cs) have been determined. The conductivities were well represented as quadratic functions of temperature. The molar conductivities for pure lanthanide chlorides were derived and represented well by an Arrhenius-type function of temperature. Electrical conduction in investigated melts was discussed on the basis of complex formation and polymerization.

引用

页码：143 / 149

页数：7

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