Catalytic properties of water-soluble rhodium and iridium complexes:: the influence of the ligand structure

被引：22

作者：

Gulyás, H

Bényei, AC

Bakos, J

机构：

[1] Univ Veszprem, Dept Organ Chem, H-8201 Veszprem, Hungary

[2] Hungarian Acad Sci, Res Grp Petrochem, H-8201 Veszprem, Hungary

[3] Univ Debrecen, Dept Chem, H-4010 Debrecen, Hungary

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 10期

基金：

匈牙利科学研究基金会;

关键词：

rhodium; iridium; water-soluble; sulfonated phosphane; homogeneous hydrogenation; aldehyde; X-ray analysis; guanidium; cone angle;

D O I：

10.1016/j.ica.2004.01.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium and iridium complexes of trisulfonated triarylphosphanes, TPPTS (tris(3-sulfonatophenyl)phosphane), T(p-A)PTS (tris(3-sulfonato-4-methoxyphenyl)phosphane), T(2,4-X)TS (tris(2,4-dimethyl-5-sulfonatophenyl)phosphane), have been tested in biphasic hydrogenation of aldehydes. T(2,4-X)TS could not stabilize the rhodium complex under the applied conditions. Guanidium salt of T(2,4-X)TS has been characterized by X-ray crystallography.. and Tolman cone angle of the phosphane has been determined from crystallographic data. The large cone angle (196degrees, 210degrees) explains the instability of the rhodium complex. Contrary to the T(2,4-X)TS/rhodium system, the T(2,4-X)TS/iridium catalyst has been found to be stable and effective in hydrogenation of benzaldehyde and caproaldehyde. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3094 / 3098

页数：5

共 35 条

[1] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92
ALTOMARE, A
CASCARANO, G
GIACOVAZZO, C
GUAGLIARDI, A
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) : 343 - 350
[2] [Anonymous], 1995, ANGEW CHEM, V107, P893
[3] COMMENTS ON THE SYNTHESIS OF TRISULFONATED TRIPHENYLPHOSPHINE - REACTION MONITORING BY NMR-SPECTROSCOPY
BARTIK, T
BARTIK, B
HANSON, BE
GLASS, T
BEBOUT, W
[J]. INORGANIC CHEMISTRY, 1992, 31 (12) : 2667 - 2670
[4] CHLOROTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) AND RELATED COMPLEXES . OXIDATIVE ADDITION REACTIONS AND HYDROGEN ABSTRACTION FROM COORDINATED LIGAND
BENNETT, MA
MILNER, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) : 6983 - &
[5] OLEFIN CO-ORDINATION COMPOUNDS .16. DIENE COMPLEXES OF RHODIUM(I)
CHATT, J
VENANZI, LM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1957, (DEC): : 4735 - 4741
[6] Bulk and fine chemicals via aqueous biphasic catalysis
Cornils, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 1 - 10
[7] Industrial aspects of aqueous catalysis
Cornils, B
Herrmann, WA
Eckl, RW
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 27 - 33
[8] INTRODUCING TPPTS AND RELATED LIGANDS FOR INDUSTRIAL BIPHASIC PROCESSES
CORNILS, B
KUNTZ, EG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 502 (1-2) : 177 - 186
[9] SULFONATED PHOSPHINES
Ding, H
Bunn, BB
Hanson, BE
Eckl, RW
Kohlpaintner, CW
Herrmann, WA
[J]. INORGANIC SYNTHESES, VOL 32, 1998, 32 : 29 - 36
[10] FARUGIA LJ, 1999, J APPL CRYSTALLOGR, V32, P937

← 1 2 3 4 →