Thermodynamic properties of binary mixtures containing 1,2-epoxybutane plus four alkanols at 298.15 K

被引:6
作者
Comelli, F
Francesconi, R
机构
[1] CNR, CTR STUDIO FIS MACROMOL, I-40126 BOLOGNA, ITALY
[2] UNIV BOLOGNA, DIPARTIMENTO CHIM G CIAMICIAN, I-40126 BOLOGNA, ITALY
关键词
D O I
10.1021/je960165g
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isothermal vapor-liquid equilibria, VLE, excess molar enthalpies, H-m(E), and excess molar volumes, V-m(E), were determined for 1,2-epoxybutane+methanol, +ethanol, +1-propanol, and +2-propanol at 298.15 K. The VLE results were correlated with the Wilson equation, and H-m(E) and V-m(E) were correlated with the Redlich-Kister equation. Nonideality of the vapor phase was accounted for in the analysis of VLE data. Azeotropes occurred in the system 1,2-epoxybutane+methanol and, to a lesser extent, for 1,2-epoxybutane+ethanol.
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页码:1392 / 1396
页数:5
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