Measurement of Two-Photon Absorption Cross Section of Metal Ions by a Mass Sedimentation Approach

被引:15
作者
Ma, Zhuo-Chen [1 ]
Chen, Qi-Dai [1 ]
Han, Bing [1 ]
Liu, Xue-Qing [1 ]
Song, Jun-Feng [1 ]
Sun, Hong-Bo [1 ,2 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Phys, Changchun 130023, Peoples R China
基金
中国国家自然科学基金;
关键词
OPTICAL-DATA STORAGE; PHOTOCHEMICAL FORMATION; QUANTUM DOTS; POLYMERIZATION; SILVER; FLUORESCENCE; INITIATORS; EXCITATION;
D O I
10.1038/srep17712
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
070301 [无机化学]; 070403 [天体物理学]; 070507 [自然资源与国土空间规划学]; 090105 [作物生产系统与生态工程];
摘要
The photo-reduction of metal ions in solution induced by femtosecond laser is an important and novel method for fabricating three-dimensional metal microstructures. However, the nonlinear absorption cross section of metal ions remains unknown because its measurement is difficult. In the present study, a method based on Two-Photon Excited Sedimentation (TPES) is proposed to measure the two-photon absorption cross section (TPACS) of metal ions in solution. The power-squared dependence of the amount of sediment on the excitation intensity was confirmed, revealing that 800 nm femtosecond laser induced reduction of metal ions was a two photon absorption process. We believe that the proposed method may be applied to measure the TPACS of several metal ions, thereby opening a new avenue towards future analysis of two-photon absorption materials.
引用
收藏
页数:8
相关论文
共 36 条
[1]
Two-photon absorption cross section measurements of various two-photon initiators for ultrashort laser radiation applying the Z-scan technique [J].
Ajami, A. ;
Husinsky, W. ;
Liska, R. ;
Pucher, N. .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2010, 27 (11) :2290-2297
[2]
Multiphoton laser direct writing of two-dimensional silver structures [J].
Baldacchini, T ;
Pons, AC ;
Pons, J ;
LaFratta, CN ;
Fourkas, JT ;
Sun, Y ;
Naughton, MJ .
OPTICS EXPRESS, 2005, 13 (04) :1275-1280
[3]
Two-photon fluorescence imaging of impurity distributions in protein crystals [J].
Caylor, CL ;
Dobrianov, I ;
Kimmer, C ;
Thorne, RE ;
Zipfel, W ;
Webb, WW .
PHYSICAL REVIEW E, 1999, 59 (04) :R3831-R3834
[4]
Two-photon-induced fluorescence from the phycoerythrin protein [J].
Chen, ZP ;
Kaplan, DL ;
Yang, K ;
Kumar, J ;
Marx, KA ;
Tripathy, SK .
APPLIED OPTICS, 1997, 36 (07) :1655-1659
[5]
Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication [J].
Cumpston, BH ;
Ananthavel, SP ;
Barlow, S ;
Dyer, DL ;
Ehrlich, JE ;
Erskine, LL ;
Heikal, AA ;
Kuebler, SM ;
Lee, IYS ;
McCord-Maughon, D ;
Qin, JQ ;
Röckel, H ;
Rumi, M ;
Wu, XL ;
Marder, SR ;
Perry, JW .
NATURE, 1999, 398 (6722) :51-54
[6]
Extremely High Brightness from Polymer-Encapsulated Quantum Dots for Two-photon Cellular and Deep-tissue Imaging [J].
Fan, Yanyan ;
Liu, Helin ;
Han, Rongcheng ;
Huang, Lu ;
Shi, Hao ;
Sha, Yinlin ;
Jiang, Yuqiang .
SCIENTIFIC REPORTS, 2015, 5
[7]
HADA H, 1976, J PHYS CHEM-US, V80, P2728, DOI 10.1021/j100566a003
[8]
Nonlinear optical properties of a new chromophore [J].
He, GS ;
Yuan, LX ;
Cheng, N ;
Bhawalkar, JD ;
Prasad, PN ;
Brott, LL ;
Clarson, SJ ;
Reinhardt, BA .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1997, 14 (05) :1079-1087
[9]
ABSOLUTE MEASUREMENT OF 2-PHOTON CROSS-SECTIONS [J].
HERMANN, JP ;
DUCUING, J .
PHYSICAL REVIEW A-GENERAL PHYSICS, 1972, 5 (06) :2557-+
[10]
Improvement in the reduction of silver ions in aqueous solution using two-photon sensitive dye [J].
Ishikawa, Atsushi ;
Tanakaa, Takuo ;
Kawata, Satoshi .
APPLIED PHYSICS LETTERS, 2006, 89 (11)