Photocatalytic oxidation of selected aryl alcohols in acetonitrile

被引：85

作者：

Mohamed, OS ^{[1
]}

Gaber, AM ^{[1
]}

Abdel-Wahab, AA ^{[1
]}

机构：

[1] Assiut Univ, Fac Sci, Dept Chem, Assiut 71516, Egypt

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2002年 / 148卷 / 1-3期

关键词：

photocatalytic oxidation; TiO2; aryl alcohols;

D O I：

10.1016/S1010-6030(02)00044-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic oxidation of selected aryl alcohols (1-7) has been carried out by using anatase titanium dioxide catalyst. The main oxidation products were the corresponding aldehydes or ketones and acids, in addition to unidentified minor compounds. Kinetic studies revealed a second-order reaction rate for benzyl alcohol, as a model alcohol, photocatalytic oxidation. The suggested mechanism envisages electron-hole pair formation on the catalyst surface followed by oxidation-reduction reactions. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：205 / 210

页数：6

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