The synthesis and structure of a new type of borosilicate cage

被引：15

作者：

Ferguson, G ^{[1
]}

OLeary, BJ ^{[1
]}

Murphy, DM ^{[1
]}

Spalding, TR ^{[1
]}

机构：

[1] UNIV COLL,DEPT CHEM,CORK,IRELAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 526卷 / 01期

关键词：

X-ray diffraction; cage; boron; borosilicate; synthesis; silicon;

D O I：

10.1016/S0022-328X(96)06468-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel borosilicate compound [(t)BuSi{O(BC6H4Br)O}(3)Si(t)Bu], 1, which contains a Si(OBO)(3)Si cage, is synthesised by the reaction of tert-butylsilanetriol with 4-bromophenylboric acid in toluene solution at reflux and structurally characterised with X-ray diffraction and spectroscopic techniques.

引用

收藏

页码：195 / 198

页数：4

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