Ferromagnetism on a paramagnetic host background:: the case of rutile TM:TiO2 single crystals (TM = Cr, Mn, Fe, Co, Ni, Cu)

被引:59
作者
Sangaletti, L.
Mozzati, M. C.
Galinetto, P.
Azzoni, C. B.
Speghini, A.
Bettinelli, M.
Calestani, G.
机构
[1] Univ Cattolica, Dipartimento Matemat & Fis, I-25121 Brescia, Italy
[2] Univ Pavia, CNISM, I-27100 Pavia, Italy
[3] Univ Pavia, Dipartimento Fis A Volta, I-27100 Pavia, Italy
[4] Univ Verona, Dipartimento Sci & Tecnol, I-37134 Verona, Italy
[5] Univ Parma, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy
关键词
D O I
10.1088/0953-8984/18/32/012
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Single crystals of TiO2 rutile doped with Cr, Mn, Fe, Co, Ni, and Cu were grown with the flux method in a Na2B4O7 melt. The samples, checked in their structural and phase homogeneity by x-ray diffraction and micro-Raman spectroscopy, were single-phase needle-shaped crystals several millimetres long. Paramagnetic and ferromagnetic behaviours at room temperature were observed and they are discussed also in connection with the magnetic properties of undoped TiO2 crystals.
引用
收藏
页码:7643 / 7650
页数:8
相关论文
共 28 条
[1]  
ANIKIN IN, 1965, SOV PHYS CRYSTALLOGR, V10, P172
[2]   The role of transition metal impurities and oxygen vacancies in the formation of ferromagnetism in Co-doped TiO2 [J].
Anisimov, VI ;
Korotin, MA ;
Nekrasov, IA ;
Mylnikova, AS ;
Lukoyanov, AV ;
Wang, JL ;
Zeng, Z .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2006, 18 (05) :1695-1704
[3]   GROWTH OF RUTILE OF CONTROLLED COMPOSITION FROM BORATE FLUXES [J].
BERKES, JS ;
WHITE, WB ;
ROY, R .
JOURNAL OF APPLIED PHYSICS, 1965, 36 (10) :3276-&
[4]  
BETTINELLI M, UNPUB
[5]   Epitaxial growth and properties of ferromagnetic co-doped TiO2 anatase [J].
Chambers, SA ;
Thevuthasan, S ;
Farrow, RFC ;
Marks, RF ;
Thiele, JU ;
Folks, L ;
Samant, MG ;
Kellock, AJ ;
Ruzycki, N ;
Ederer, DL ;
Diebold, U .
APPLIED PHYSICS LETTERS, 2001, 79 (21) :3467-3469
[6]  
CHEN JS, 2005, APPL PHYS LETT, V86
[7]  
Cotton F. A., 1972, ADV INORG CHEM, P1145
[8]   Appearance of room-temperature ferromagnetism in Cu-doped TiO2-δ films -: art. no. 161313 [J].
Duhalde, S ;
Vignolo, MF ;
Golmar, F ;
Chiliotte, C ;
Torres, CER ;
Errico, LA ;
Cabrera, AF ;
Rentería, M ;
Sánchez, FH ;
Weissmann, M .
PHYSICAL REVIEW B, 2005, 72 (16)
[9]  
GARTON G, 1971, J CRYST GROWTH, V13, P588
[10]   Co distribution in ferromagnetic rutile Co-doped TiO2 thin films grown by laser ablation on silicon substrates [J].
Hong, NH ;
Sakai, J ;
Prellier, W ;
Hassini, A .
APPLIED PHYSICS LETTERS, 2003, 83 (15) :3129-3131