Tellurium in organic synthesis:: an approach to the synthesis of (Z,E)-dienic precursors of insect pheromones

被引：10

作者：

Diego, Dennis G. ^{[1
]}

Cunha, Rodrigo L. O. R. ^{[1
]}

Comasseto, Joao V. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 40期

基金：

巴西圣保罗研究基金会;

关键词：

D O I：

10.1016/j.tetlet.2006.08.005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and straightforward route to (Z,E)-dienic precursors of insect pheromones was developed. The route features a cross-coupling of a (Z,E)-dienic telluride with an alkyl Lipshutz cuprate. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：7147 / 7148

页数：2

共 17 条

[1]

Brandsma L, 1988, PREPARATIVE ACETYLEN

[2] SYNTHESIS OF LOBESIA-BOTRANA AND SPODOPTERA-LITTORALIS NATURAL SEX-ATTRACTANTS [J].

CASSANI, G ;

MASSARDO, P ;

PICCARDI, P .

TETRAHEDRON LETTERS, 1980, 21 (36) :3497-3498

[3] Diastereoselective synthesis of α,β-unsaturated systems [J].

Castelani, P ;

Comasseto, JV .

TETRAHEDRON, 2005, 61 (09) :2319-2326

[4] Substitution reaction between functionalized Z-vinylic tellurides and lower order cyanocuprates.: Synthesis of Z or E α,β unsaturated esters using the same Z-vinylic telluride [J].

Castelani, P ;

Comasseto, JV .

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2004, 15 (04) :461-463

[5]

CHIEFFI A, 1995, SYNLETT, P671

[6] INFLUENCE OF THE GEGENION IN THE TRANSMETALATION REACTION OF VINYLIC TELLURIDES WITH HIGHER-ORDER CYANOCUPRATES [J].

CHIEFFI, A ;

COMASSETO, JV .

TETRAHEDRON LETTERS, 1994, 35 (24) :4063-4066

[7]

Krause N., 2001, MODERN ORGANOCOPPER

[8] Stereocontrolled synthesis of (-)-macrolactin A [J].

Marino, JP ;

McClure, MS ;

Holub, DP ;

Comasseto, JV ;

Tucci, FC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (08) :1664-1668

[9] Useful reactions in modern pheromone synthesis [J].

Mori, K ;

Tashiro, T .

CURRENT ORGANIC SYNTHESIS, 2004, 1 (01) :11-29

[10]

MORI K, 1992, TOTAL SYNTHESIS NATU

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