Synthesis of nearly monodisperse palladium (Pd) nanoparticles by using oleylamine and trioctylphosphine mixed ligands

被引：56

作者：

Yang, Zhiqiang ^{[1
]}

Klabunde, Kenneth J. ^{[1
]}

机构：

[1] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 7-8期

关键词：

Palladium; Pd; Nanoparticles; Monodisperse; Oleylamine; Trioctylphosphine; SIZE; GOLD; NANOCRYSTALS; REACTIVITY; STABILITY; OXIDATION; PLATINUM; CLUSTERS; SYSTEM;

D O I：

10.1016/j.jorganchem.2008.11.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, we report a facile method to prepare nearly monodisperse Pd nanoparticles by heating Pd(II) ions in 4-tert-butyltoluene solvent, in the presence of oleylamine and trioctylphosphine (TOP) ligands. It has been found the concentration of TOP ligand was highly pivotal for the formation of Pd nanoparticles. Without TOP, only aggregated Pd particles were obtained due to the reduction of Pd(II) by oleylamine. When the molar ratio of TOP to Pd(II) was less than two, well-protected Pd nanoparticles were obtained. However, when the molar ratio reached to two, only Pd(II)-TOP coordination complexes were obtained as the final product. Also, the addition of excess oleylamine as a supplementary protecting ligand has proven to be very important. By controlling the experimental conditions, Pd nanoparticles were obtained by this simple synthetic process, and the average size controllable in the range of 9.5-14.9 nm, with standard deviation in the range of 8-13%. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1016 / 1021

页数：6

共 27 条

[1] Novel one-step synthesis of amine-stabilized aqueous colloidal gold nanoparticles [J].

Aslam, M ;

Fu, L ;

Su, M ;

Vijayamohanan, K ;

Dravid, VP .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (12) :1795-1797

[2] MECHANISM OF PRIMARY ALIPHATIC-AMINES OXIDATION TO NITRILES BY THE CUPROUS CHLORIDE-DIOXYGEN-PYRIDINE SYSTEM [J].

CAPDEVIELLE, P ;

LAVIGNE, A ;

SPARFEL, D ;

BARANNELAFONT, J ;

CUONG, NK ;

MAUMY, M .

TETRAHEDRON LETTERS, 1990, 31 (23) :3305-3308

[3] Synthesis and self-organization of soluble monodisperse palladium nanoclusters [J].

Chen, M ;

Falkner, J ;

Guo, WH ;

Zhang, JY ;

Sayes, C ;

Colvin, VL .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 287 (01) :146-151

[4] Monodisperse thioether-stabilized palladium nanoparticles: Synthesis, characterization, and reactivity [J].

Ganesan, Mani ;

Freemantle, Ruel G. ;

Obare, Sherine O. .

CHEMISTRY OF MATERIALS, 2007, 19 (14) :3464-3471

[5] A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants [J].

Hiramatsu, H ;

Osterloh, FE .

CHEMISTRY OF MATERIALS, 2004, 16 (13) :2509-2511

[6] Hydrogen storage properties of isocyanide-stabilized palladium nanoparticles [J].

Horinouchi, S ;

Yamanoi, Y ;

Yonezawa, T ;

Mouri, T ;

Nishihara, H .

LANGMUIR, 2006, 22 (04) :1880-1884

[7] Synthesis of monodisperse palladium nanoparticles [J].

Kim, SW ;

Park, J ;

Jang, Y ;

Chung, Y ;

Hwang, S ;

Hyeon, T ;

Kim, YW .

NANO LETTERS, 2003, 3 (09) :1289-1291

[8]

Klabunde K.J., 2001, NANOSCALE MAT CHEM

[9] Superlattices of platinum and palladium nanoparticles [J].

Martin, JE ;

Wilcoxon, JP ;

Odinek, J ;

Provencio, P .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (05) :971-978

[10] Effect of catalysis on the stability of metallic nanoparticles: Suzuki reaction catalyzed by PVP-palladium nanoparticles [J].

Narayanan, R ;

El-Sayed, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (27) :8340-8347

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