The valence states of vanadium in the low-temperature superstructure of NaV2O5

被引：26

作者：

Van Smaalen, S ^{[1
]}

Lüdecke, J ^{[1
]}

机构：

[1] Univ Bayreuth, Crystallog Lab, D-95440 Bayreuth, Germany

来源：

EUROPHYSICS LETTERS | 2000年 / 49卷 / 02期

关键词：

D O I：

10.1209/epl/i2000-00141-0

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We have applied the bond-valence method to calculate the valencies of the vanadium atoms in the low-temperature superstructure of alpha'-NaV2O5. The modulated ladders are found to comprise V4+ and V5+ cations in a zigzag type of charge order. The non-modulated ladders comprise a single type of vanadium atom in the mixed-valence state V4.5+.

引用

页码：250 / 254

页数：5

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