An unexpected zinc coordination polymer formed during the preparation of 5-substituted 1H-tetrazoles from a nitrile in water

被引：63

作者：

Xue, X

Abrahams, BF ^{[1
]}

Xiong, RG

You, XZ

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 08期

关键词：

D O I：

10.1071/CH02089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of N, N'-dicyanohydrazine with ZnCl2 and NaN3 in water unexpectedly affords 5-aminotetrazolato hydroxo zinc rather than a zinc complex with bis(tetrazolyl) hydrazine. An N-N bond cleavage has occurred in the Demko-Sharpless' tetrazole synthesis.

引用

页码：495 / 497

页数：3

共 23 条

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Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[2]

2-Z

[3] Thallium(I)- and organothallium(III)-substituted mono-, bis- and tris-tetrazoles: synthesis and supramolecular structures [J].