Radioactive iodine waste treatment using electrodialysis with an anion exchange paper membrane

被引：31

作者：

Inoue, H ^{[1
]}

Kagoshima, M ^{[1
]}

Yamasaki, M ^{[1
]}

Honda, Y ^{[1
]}

机构：

[1] Kurume Univ, Sch Med, Radioisotope Inst Basic & Clin Med, Kurume, Fukuoka 8300011, Japan

来源：

APPLIED RADIATION AND ISOTOPES | 2004年 / 61卷 / 06期

关键词：

radioactive iodine; electrodialysis; anion exchange paper membrane;

D O I：

10.1016/j.apradiso.2004.04.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In order to simply and safely treat radioactive iodine waste, a study of the removal of iodide ion from radioactive waste using electrodialysis with an anion exchange paper membrane, in which trimethylhydroxylpropylammonium groups were homogeneously dispersed with high density. In (NaI)-I-125 and (NaCl)-Cl-36 concentration-cell system, electric ion and water conductances, phenomenological coefficients, have been experimentally determined on basis of nonequilibrium thermodynamics. Prepared paper membrane had higher permselectivity of I-125 ion than Cl-36 ions by approximately 21%. On the other hand, water flux that was accompanied by an ionic transference in prepared paper membrane was greatly larger than that in typical synthesized membrane. It is suggested that a depression of water mobility is important to practice an ideal radioactive iodide waste electrodialysis system with a novel anion exchange paper membrane. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1189 / 1193

页数：5

共 14 条

[1]

BOHNER KE, 1983, P 9 BIENN C CAMP RAD, P23

[2] I-125 aqueous waste volume reduction at a pharmaceutical research laboratory [J].

Edwards, BE ;

Couch, NW ;

Myers, KD ;

Blanchard, SG ;

Chandra, G ;

Parr, AF .

HEALTH PHYSICS, 1996, 71 (03) :379-383

[3]

Helfferich F., 1995, ION EXCHANGE

[4] Removal of 125I from radioactive experimental waste with an anion exchange paper membrane [J].

Inoue, H ;

Kagoshima, M .

APPLIED RADIATION AND ISOTOPES, 2000, 52 (06) :1407-1412

[5] Effects of co-ions on transport of iodide ions through a non-conventional anion exchange paper membrane [J].

Inoue, H .

JOURNAL OF MEMBRANE SCIENCE, 2004, 228 (02) :209-215

[6] Radioactive iodine and chloride transport across a paper membrane bearing trimethylhydroxypropylammonium anion exchange groups [J].

Inoue, H .

JOURNAL OF MEMBRANE SCIENCE, 2003, 222 (1-2) :53-57

[7] Transport of 125I and 36Cl across an anion-exchange paper membrane [J].

Inoue, H .

APPLIED RADIATION AND ISOTOPES, 2002, 56 (05) :659-665

[8] Influence of glucose and urea on 125I transport across an anion exchange paper membrane [J].

Inoue, H .

APPLIED RADIATION AND ISOTOPES, 2001, 54 (04) :595-602

[9]

KATCHALSKY A, 1964, NONEQUILIBRIUM THERM

[10] Individual activity coefficients of ions in aqueous solutions [J].

Kielland, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :1675-1678

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