Synthesis and coordination chemistry of a water-soluble verdazyl radical.: structures and magnetic properties of M(H2O)2(vdCO2)2•2H2O (M = Co, Ni; vdCO2=1,5-dimethyl-6-oxo-verdazyl-3-carboxylate)

被引:50
作者
Barclay, TM
Hicks, RG
Lemaire, MT
Thompson, LK
Xu, ZQ
机构
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
[2] N Harris Coll, Dept Chem, Houston, TX 77073 USA
[3] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada
关键词
D O I
10.1039/b204851e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a verdazyl radical with a carboxylate substituent renders the radical highly soluble in water, thereby permitting the aqueous synthesis of Ni(II) and Co(II) verdazyl complexes which have been structurally and magnetically characterized.
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页码:1688 / 1689
页数:2
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