Studies of the thermal decomposition of (2-thiazolin-2-yl)hydrazine hydrochloride and some metal derivative complexes

被引：16

作者：

Bernalte-García, A

García-Barros, FJ

Higes-Rolando, FJ ^{[1
]}

Pizarro-Galán, AM

Valenzuela-Calahorro, C

机构：

[1] Univ Extremadura, Fac Ciencias, Dept Quim Inorgan, E-06071 Badajoz, Spain

[2] Univ Granada, Fac Farm, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

THERMOCHIMICA ACTA | 1999年 / 339卷 / 1-2期

关键词：

hydrazine; thiazoline; DSC; TG; spectroscopic studies;

D O I：

10.1016/S0040-6031(99)00224-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The compound (2-thiazolin-2-yl)hydrazine hydrochloride (TzHyHCl) and the complexes [Ni(TzHy)(2)(H2O)(2)]Cl-2 . 2H(2)O, [ZnCl(TzHy)(2)]Cl and [Cd(TzHy)(mu-Cl)(2)](n). nH(2)O have been studied using spectral (LR and electronic) and thermal (TG and DSC) methods. (C) 1999 Published by Elsevier Science B.V. All rights reserved.

引用

收藏

页码：95 / 101

页数：7

相关论文

共 22 条

[1] DERIVATIVES OF HYDRAZINE .I. PREPARATION AND INFRARED SPECTRA OF PARTIALLY DEUTERATED MONO- AND DIMETHYLHYDRAZINES [J].

ANTHONI, U ;

LARSEN, C ;

NIELSEN, PH .

ACTA CHEMICA SCANDINAVICA, 1968, 22 (03) :1025-&

[2]

Bellamy L. J., 1954, The Infrared Spectra of Complex Molecules

[3] The coordination chemistry of (2-thiazolin-2-yl)hydrazine hydrochloride (TzHyHCl) .1. Crystal structure of the ligand and study of its interaction with nickel(II) [J].

BernalteGarcia, A ;

DiazDiez, MA ;

GarciaBarros, FJ ;

HigesRolando, FJ ;

PizarroGalan, AM ;

RomeroGarzon, J ;

ValenzuelaCalahorro, C .

POLYHEDRON, 1996, 15 (10) :1691-1697

[4] The coordination chemistry of (2-thiazolin-2-yl)hydrazine hydrochloride (TzHyHCl) .2. Study of its interaction with zinc(II) and cadmium(II) [J].

BernalteGarcia, A ;

DiazDiez, MA ;

GarciaBarros, FJ ;

HigesRolando, FJ ;

PizarroGalan, AM ;

MartinRamos, JD ;

ValenzuelaCalahorro, C .

POLYHEDRON, 1997, 16 (02) :297-305

[5]

BRUGAROLAS A, 1979, LANCET, V68, P1

[6] RELATION BETWEEN STRUCTURES AND SPECTROSCOPIC PROPERTIES OF GROUP-2B METAL [M(CHELATE)X2] COMPLEXES (X=CL,BR,I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [H2NCH2(CH3)2CCH2NH2]MX2 COMPLEXES (M=ZN,X=CL, BR,M=CD, X=BR) [J].

CARIATI, F ;

CIANI, G ;

MENABUE, L ;

PELLACANI, GC ;

RASSU, G ;

SIRONI, A .

INORGANIC CHEMISTRY, 1983, 22 (13) :1897-1902

[7] SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF HIGH-SPIN CHROMIUM(II) AND COPPER(II) COMPLEXES WITH BIDENTATE ALPHA,ALPHA'-DIIMINE LIGANDS-2,2'-PYRIDYLBENZIMIDAZOLE'2,2'-PYRIDYLIMIDAZOLE AND 2,2'-PYRIDYLIMIDAZOLINE [J].

DECASTRO, B ;

FREIRE, C ;

DOMINGUES, D ;

GOMES, J .

POLYHEDRON, 1991, 10 (22) :2541-2549

[8]

DURIG JR, 1974, J CHEM PHYS, V60, P253

[9]

DUVAL C, 1953, INORGANIC THERMOGRAV

[10]

Ferraro J.R., 1971, Low-Frequency Vibrations of Inorganic and Coordination Compounds