Localized (3)MLCT excitations of [Ru(bpy)(3-x)(bpy-6,6'-d(2))(x)](2+) (x=0-3) in [Zn(bpy)(3)](ClO4)(2) (bpy=2,2'-bipyridine)

被引：10

作者：

Riesen, H

Wallace, L

Krausz, E

机构：

[1] Research School of Chemistry, Australian National University, Canberra

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 24期

关键词：

D O I：

10.1021/ic960590v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Luminescence and excitation spectra of specifically deuterated complexes [Ru(bpy)(3-x)-(bpy-6,6'-d(2))(x)](2+) (x = 0-3) doped into [Zn(bpy)(3)](ClO4)(2) are reported. Independent (3)MLCT transitions to the bpy-6,6'-d(2) and bpy ligand are observed for the x = 1, 2 systems. The transferred charge in the lowest excited (3)MLCT states is invariably localized.

引用

页码：6908 / +

共 22 条

[1] VIBRATIONAL SPECTROSCOPY OF THE ELECTRONICALLY EXCITED-STATE .5. TIME-RESOLVED RESONANCE RAMAN-STUDY OF TRIS(BIPYRIDINE)RUTHENIUM(II) AND RELATED COMPLEXES - DEFINITIVE EVIDENCE FOR THE LOCALIZED MLCT STATE
BRADLEY, PG
KRESS, N
HORNBERGER, BA
DALLINGER, RF
WOODRUFF, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (25) : 7441 - 7446
[2] CAROLL PJ, 1987, J AM CHEM SOC, V109, P7613
[3] MOLECULAR AND ELECTRONIC-STRUCTURE IN THE METAL-TO-LIGAND CHARGE-TRANSFER EXCITED-STATES OF D6 TRANSITION-METAL COMPLEXES IN SOLUTION
CASPAR, JV
WESTMORELAND, TD
ALLEN, GH
BRADLEY, PG
MEYER, TJ
WOODRUFF, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (12) : 3492 - 3500
[4] Characterization of the lowest excited states of [Rh(bpy-h(8))(n)(bpy-d(8))(3-n)](3+) by highly resolved emission and excitation spectra
Humbs, W
Yersin, H
[J]. INORGANIC CHEMISTRY, 1996, 35 (08) : 2220 - 2228
[5] EXCITED-STATE PROPERTIES OF A (2,2'-BIPYRIDINE)RUTHENIUM(II) COMPLEX, [RU(CN)4(BPY)]2-, A MODEL OF LOCALIZED EXCITATION
KATO, M
YAMAUCHI, S
HIROTA, N
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (09) : 3422 - 3425
[6] CRYSTAL-STRUCTURES OF AND POLARIZED ABSORPTION-SPECTROSCOPY IN RACEMIC AND RESOLVED [RU(BPY)(3)] (CLO4)(2) AND [ZN(BPY)(3)] (CLO4)(2)BPY=2,2'-BIPYRIDINE
KRAUSZ, E
RIESEN, H
RAE, AD
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1995, 48 (05) : 929 - 954
[7] INTERLIGAND ELECTRON-TRANSFER AND TRANSITION-STATE DYNAMICS IN RU(II)TRISBIPYRIDINE
MALONE, RA
KELLEY, DF
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (12) : 8970 - 8976
[8] VIBRATIONAL-SPECTRA OF SPECIFICALLY DEUTERIATED 2,2'-BIPYRIDINE COMPLEXES OF FE(II), RU(II) AND OS(II)
MCCLANAHAN, S
KINCAID, J
[J]. JOURNAL OF RAMAN SPECTROSCOPY, 1984, 15 (03) : 173 - 178
[9] Riesen H, 1996, MOL PHYS, V87, P1299
[10] Dynamic processes in the lowest-excited (3)MLCT states of [M(L)(3-x)(L')(x)](2+) (L,L'=diimine; M=Ru,Os)
Riesen, H
Krausz, E
[J]. COMMENTS ON INORGANIC CHEMISTRY, 1995, 18 (01) : 27 - 63

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