Characterization of volatile compounds of French and Spanish virgin olive oils by HS-SPME: Identification of quality-freshness markers

被引:151
作者
Cavalli, JF [1 ]
Fernandez, X [1 ]
Lizzani-Cuvelier, L [1 ]
Loiseau, AM [1 ]
机构
[1] Univ Nice, Fac Sci, Lab Aromes Synth & Interact, F-06108 Nice 2, France
关键词
headspace-solid phase microextraction; GC-FID; GC-MS; olive oil composition; lipoxygenase pathway;
D O I
10.1016/j.foodchem.2004.04.003
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Headspace-Solid Phase Microextraction (HS-SPME) was applied to the analysis of volatile compounds of virgin olive oils from southern France (Alpes-Maritimes) and Spain (Reus). Forty one compounds were isolated and characterized by GC-RI and GCMS, representing 85.3-92.8% of the total amount. (E)-Hex-2-enal, the main compound extracted by SPME, characterized the olive oil headspace for all samples. The other compounds identified were mainly hexanal, (Z)-hex-3-enol, (E)-hex-2-enol and hexanol. Changes in the chemical composition of the olive oil headspace were also monitored during storage. The content of (E)-hex-2-enal decreased over several months, and that of the C-6 alcohols and C-5 ketones increased. These compounds can be used as markers for the evaluation of olive oil quality. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:151 / 157
页数:7
相关论文
共 23 条
[1]   Development of a headspace solid-phase microextraction procedure for the determination of free volatile fatty acids in waste waters [J].
Abalos, M ;
Bayona, JM ;
Pawliszyn, J .
JOURNAL OF CHROMATOGRAPHY A, 2000, 873 (01) :107-115
[2]  
Angerosa F, 2002, EUR J LIPID SCI TECH, V104, P639, DOI 10.1002/1438-9312(200210)104:9/10<639::AID-EJLT639>3.0.CO
[3]  
2-U
[4]   Virgin olive oil volatile compounds from lipoxygenase pathway and characterization of some Italian cultivars [J].
Angerosa, F ;
Basti, C ;
Vito, R .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (03) :836-839
[5]   Characterization of seven new hydrocarbon compounds present in the aroma of virgin olive oils [J].
Angerosa, F ;
Camera, L ;
d'Alessandro, N ;
Mellerio, G .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (02) :648-653
[6]   Authentication of vegetable oils by chromatographic techniques [J].
Aparicio, R ;
Aparicio-Ruíz, R .
JOURNAL OF CHROMATOGRAPHY A, 2000, 881 (1-2) :93-104
[7]   SOLID-PHASE MICROEXTRACTION WITH THERMAL-DESORPTION USING FUSED-SILICA OPTICAL FIBERS [J].
ARTHUR, CL ;
PAWLISZYN, J .
ANALYTICAL CHEMISTRY, 1990, 62 (19) :2145-2148
[8]   Sorptive sample preparation - a review [J].
Baltussen, E ;
Cramers, CA ;
Sandra, PJF .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 373 (1-2) :3-22
[9]   Assay of aroma active components of virgin olive oils from southern Italian regions by SPME-GC/ion trap mass spectrometry [J].
Benincasa, C ;
De Nino, A ;
Lombardo, N ;
Perri, E ;
Sindona, G ;
Tagarelli, A .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (03) :733-741
[10]  
Bentivenga G., 2001, Rivista Italiana delle Sostanze Grasse, V78, P157