Carbon-nanotube-based glucose/O2 biofuel cells

被引:220
作者
Yan, Yiming [1 ]
Zheng, Wei [1 ]
Su, Lei [1 ]
Mao, Lanqun [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
D O I
10.1002/adma.200600028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A single-walled carbon nanotube (SWNT)-based enzymatic glucose/O-2 biofuel cell with a high voltage is demonstrated. The fuel cell uses glucose dehydrogenase as the anode biocatalyst for the oxidation of glucose, and laccase as the cathode biocatalyst for the reduction Of O-2 (see figure). The SWNTs are used as electrode materials, as a support for electrocatalysts and biocatalysts, and for facilitating the direct electron transfer of laccase.
引用
收藏
页码:2639 / +
页数:6
相关论文
共 54 条
[1]   Nanotubes from carbon [J].
Ajayan, PM .
CHEMICAL REVIEWS, 1999, 99 (07) :1787-1799
[2]   Development of alcohol/O2 biofuel cells using salt-extracted tetrabutylammonium bromide/Nafion membranes to immobilize dehydrogenase enzymes [J].
Akers, NL ;
Moore, CM ;
Minteer, SD .
ELECTROCHIMICA ACTA, 2005, 50 (12) :2521-2525
[3]   Targetting redox polymers as mediators for laccase oxygen reduction in a membrane-less biofuel cell [J].
Barrière, F ;
Ferry, Y ;
Rochefort, D ;
Leech, D .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (03) :237-241
[4]   Enzymatic biofuel cells for Implantable and microscale devices [J].
Barton, SC ;
Gallaway, J ;
Atanassov, P .
CHEMICAL REVIEWS, 2004, 104 (10) :4867-4886
[5]   Electroreduction of O2 to water at 0.6 V (SHE) at pH 7 on the 'wired' Pleurotus ostreatus laccase cathode [J].
Barton, SC ;
Pickard, M ;
Vazquez-Duhalt, R ;
Heller, A .
BIOSENSORS & BIOELECTRONICS, 2002, 17 (11-12) :1071-1074
[6]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[7]   Biofuel cells and their development [J].
Bullen, RA ;
Arnot, TC ;
Lakeman, JB ;
Walsh, FC .
BIOSENSORS & BIOELECTRONICS, 2006, 21 (11) :2015-2045
[8]   A miniature biofuel cell [J].
Chen, T ;
Barton, SC ;
Binyamin, G ;
Gao, ZQ ;
Zhang, YC ;
Kim, HH ;
Heller, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) :8630-8631
[9]  
Dong LW, 1996, J MOL RECOGNIT, V9, P383, DOI 10.1002/(SICI)1099-1352(199634/12)9:5/6<383::AID-JMR269>3.0.CO
[10]  
2-Z