Low-frequency Raman study of the ferroelectric phase transition in a layered CuCl4-based organic-inorganic hybrid

被引：23

作者：

Caretta, Antonio ^{[1
]}

Miranti, Rany ^{[1
]}

Havenith, Remco W. A. ^{[1
]}

Rampi, Elia ^{[1
]}

Donker, Michiel C. ^{[1
]}

Blake, Graeme R. ^{[1
]}

Montagnese, Matteo ^{[1
]}

Polyakov, Alexey O. ^{[1
]}

Broer, Ria ^{[1
]}

Palstra, Thomas T. M. ^{[1
]}

van Loosdrecht, Paul H. M. ^{[1
]}

机构：

[1] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands

来源：

PHYSICAL REVIEW B | 2014年 / 89卷 / 02期

关键词：

X-RAY-DIFFRACTION; LATTICE-DYNAMICS; ORDER-DISORDER; AB-INITIO; SOFT-MODE; OPTICAL INVESTIGATIONS; MAGNETIC MEASUREMENTS; NEUTRON-SCATTERING; (CH3NH3)2 CDCL4; CRYSTAL;

D O I：

10.1103/PhysRevB.89.024301

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The ferroelectric phase transition at T-C = 340 K in (C6H5CH2CH2NH3)(2)CuCl4 is studied by means of temperature-dependent low-frequency Raman scattering, focusing on the coupling of a low-energy librational mode to the order parameter of the transition. Analysis of the symmetry and characteristics of this mode links the dipolar order to the tilt angle of the organic cations. The thermal evolution of the Raman spectrum demonstrates the displacive component of the phase transition in combination with order-disorder phenomena and the importance of the organic-inorganic interplay to the physical properties of the compound. The ferroelectric properties investigated here can be generalized to the family of layered organic-inorganic hybrids.

引用

页数：9

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